Mentari, gadis pencoba racun, setiap hari tersiksa habis-habisan oleh Raja Racun, menjalani sepuluh tahun hidup penuh derita yang kejam. Sampai akhirnya ditemukan kembali oleh ibu tirinya dan dipaksa menikah sebagai ganti. Tanpa disangka, ia malah menjadi satu-satunya penawar bagi Jenderal Penjaga Negara, Glenn. Sejak saat itu, Mentari mulai menjalani hari-hari yang dimanjakan dan disayangi semua orang. Suami istri menjadi satu tubuh, dan Mentari pun menjelma menjadi nyonya utama yang tak berani diganggu siapa pun lagi.
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