Nafisa Sidjaja, untuk menyelamatkan adik laki-laki yang koma, terpaksa menikah dengan cucu tertua Keluarga Soekotjo. Tapi saat pertunangan, dia terkejut mengetahui calon suami dan sekretarisnya sudah punya hubungan gelap, bahkan ingin membahayakan hidupnya setelah menikah! Dalam situasi putus asa, Nafisa langsung mendekati Carlos Soekotjo — adik tiri Keluarga Soekotjo yang paling sulit dihadapi dan musuh Novan. Dengan menggoda dan menguji langkah demi langkah, dia ingin mengganti pasangan demi keselamatan, tapi berulang kali dibalik dan dilindungi oleh pria dingin ini. Perhitungan berubah jadi perasaan, tapi pernikahannya hanya untuk menyelamatkan adik.
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